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    • 专利摘要:
    The invention relates to a tire comprising a rubber composition based on at least one diene elastomer, a reinforcing filler, a specific polyfunctional acrylate derivative and a peroxide, the levels of polyfunctional acrylate derivative and peroxide being such that the ratio of the level of polyfunctional acrylate derivative to the peroxide level is greater than or equal to 6.
    公开号:FR3030543A1
    申请号:FR1463045
    申请日:2014-12-22
    公开日:2016-06-24
    发明作者:Delphine Nayrat
    申请人:Michelin Recherche et Technique SA Switzerland ；Compagnie Generale des Etablissements Michelin SCA；Michelin Recherche et Technique SA France；
    IPC主号:
    专利说明:

    [0001] The invention relates to tires and more particularly to those comprising a composition which comprises a polyfunctional acrylate derivative and a peroxide. Compositions comprising zinc diacrylate derivatives are described in certain state of the art documents for objects that are not tires. For example, US 2003/0065076 discloses military tank track compositions comprising an elastomer, a reinforcing filler, zinc diacrylate or zinc dimethacrylate, and a peroxide; with the effect of improving the resistance to abrasion.
    [0002] Similarly, US 2005/0084638 discloses coating mix compositions of an air sleeve for suspensions, also comprising an elastomer, a reinforcing filler, zinc diacrylate and a peroxide.
    [0003] In the specific area of tires, since fuel savings and the need to protect the environment have become a priority, it has been necessary to produce tires with reduced rolling resistance, without penalizing the other properties of the tire. . This constraint, true in all tire compositions, is particularly strong for tire treads. The manufacturers have developed tire compositions that make it possible to reduce this rolling resistance, in various ways and in particular by introducing silica into the mixtures as a reinforcing filler.
    [0004] Nevertheless, manufacturers are still seeking solutions to further reduce the rolling resistance of tire treads, and it is in this context that the applicants surprisingly discovered that hysteresis could be significantly reduced in rubber compositions for pneumatic, with a reduced rate of reinforcing filler, the composition comprising a polyfunctional acrylate derivative and a peroxide, provided to adopt a ratio between the peroxide level and the level of polyfunctional acrylate derivative adapted. Furthermore, this solution has many other advantages over the compositions of the prior art and in particular improved resistance to aging under thermal and thermo-oxidative conditions. The invention therefore relates to a tire comprising a rubber composition based on at least one diene elastomer, a reinforcing filler, a polyfunctional acrylate derivative of formula (Ia) or (Ib) / R2 R1 R3 (the ) Wherein R1, R2 and R3 independently represent a hydrogen atom or a C1-07 hydrocarbon group selected from the group consisting of linear, branched or cyclic alkyls, aralkyl groups; , alkylaryl groups and aryl groups, and optionally interrupted by one or more heteroatoms, R2 and R3 may together form a non-aromatic ring, n represents an integer of value 1, 2 or 3, and in the case of a derivative of polyfunctional acrylate of formula (Ia), R4 represents a radical selected from the group consisting of a hydrogen atom, a methyl group, an ethyl group, a propyl group or an isopropyl group, the said composition further comprising a ratio of the level of polyfunctional acrylate derivative to the peroxide level is greater than or equal to a tire as defined above, wherein R1, R2 and R3 independently represent a hydrogen atom or a methyl group. Preferably, R2 and R3 each represent a hydrogen atom. Preferentially also, R 1 represents a methyl group. Preferably, n represents the integer number 1. According to a preferred embodiment, the invention relates to a tire as defined above, in which the polyfunctional acrylate derivative is a compound of formula (Ia). Preferably, R4 represents an ethyl group. According to another preferred embodiment, the invention relates to a tire as defined above, in which the polyfunctional acrylate derivative is a compound of formula (Ib).
    [0005] Preferably, the invention relates to a tire as defined above, in which the amount of polyfunctional acrylate derivative in the composition is in a range from 10 to 70 phr (parts by weight per hundred parts by weight). elastomer), preferably from 10 to 60 phr.
    [0006] Preferably, the invention relates to a tire as defined above, wherein the peroxide in the composition is an organic peroxide. Preferably, the amount of peroxide in the composition is less than or equal to 3 phr. More preferably, the amount of peroxide in the composition is in a range from 0.1 to 3 phr. Preferably, the amount of peroxide in the composition is in a range from 0.2 to 2 phr, preferably from 0.25 to 1 phr. Preferably, the invention relates to a tire as defined above, in which the ratio of the level of polyfunctional acrylate derivative to the peroxide level is greater than or equal to 7, preferably greater than or equal to 8 and more. preferably greater than or equal to 10. More preferably, the ratio of the level of polyfunctional acrylate derivative to the peroxide content is between 10 and 110, preferably between 10 and 70, and more preferably between 10 and 40.
    [0007] Preferably, the invention relates to a tire as defined above, in which the diene elastomer is chosen from the group consisting of polybutadienes, synthetic polyisoprenes, natural rubber, butadiene copolymers, copolymers of isoprene and mixtures of these elastomers. Preferably, the diene elastomer is chosen from the group consisting of polybutadienes, synthetic polyisoprenes, natural rubber, butadiene and styrene copolymers, butadiene and acrylonitrile copolymers, isoprene and styrene and mixtures of these elastomers. Also preferably, the invention relates to a tire as defined above, wherein the composition comprises less than 50 phr of reinforcing filler.
    [0008] Preferably, the level of reinforcing filler is in a range from 5 to 45 phr. More preferably, the level of reinforcing filler is in a range from 10 to 40 phr, preferably from 15 to 35 phr. Preferably, the reinforcing filler is carbon black, silica or a mixture thereof. Preferably, the reinforcing filler is predominantly made of carbon black. Alternatively and preferentially also, the reinforcing filler is mainly composed of silica. Preferably, the invention relates to a tire as defined above, in which the ratio of the charge ratio and the level of polyfunctional acrylate derivative is less than or equal to 3.5; preferably, less than or equal to 3. Preferably, the ratio of the charge ratio and the level of polyfunctional acrylate derivative is in a range from 0.3 to 3; preferably from 1 to 3. Preferably, the invention relates to a tire as defined above, wherein the composition does not contain molecular sulfur or sulfur-donor agent as vulcanizing agent or contains less than 0.5 phr. Preferably, the composition does not contain molecular sulfur or sulfur donor agent as the vulcanizing agent or contains less than 0.3 phr and preferably less than 0.1 phr.
    [0009] Preferably, the invention relates to a tire as defined above, in which the composition does not contain a vulcanization accelerator. Also preferably, the composition does not contain an antioxidant.
    [0010] Preferably also, the invention relates to a tire as defined above, wherein the composition further comprises a plasticizer, preferably selected from plasticizing resins, extension oils and mixtures thereof. Preferably, the invention relates to a tire as defined above, wherein the composition as specified above is that of the tread, or an inner layer of said tire. Preferably, the tire according to the invention will be chosen from tires intended to equip a two-wheeled vehicle, a passenger vehicle, or a so-called "heavy vehicle" (that is to say, subway, bus, vehicles outside). road transport, road transport equipment such as trucks, tractors, trailers), or aircraft, civil engineering, agrarian, or handling equipment. I- Constituents of the tire composition The tire rubber composition according to the invention is based on the following constituents: a polyfunctional acrylate derivative of formula (I) and a peroxide, the levels of polyfunctional acrylate derivative and of peroxide being such that the ratio of the level of polyfunctional acrylate derivative to the level of peroxide is greater than or equal to 6.
    [0011] In the present application, the term "phr" ("phr") means in known manner parts by weight per hundred parts by weight of elastomer. The quantity by weight of the constituents of the compositions is thus expressed relative to the total amount of elastomers by weight conventionally considered to be the hundred value.
    [0012] By the term "composition based on" is meant a composition comprising the mixture and / or the reaction product in situ of the various basic constituents used, some of these constituents being able to react and / or being intended to react with one another, at least partially, during the various phases of manufacture of the composition, or during subsequent firing, modifying the composition as it was initially prepared. Thus, the compositions as implemented for the invention may be different in the uncrosslinked state and in the crosslinked state. When reference is made to a "majority" compound, in the sense of the present invention, it is understood that this compound is predominant among the compounds of the same type in the composition, that is to say that it is the one which represents the largest amount by mass among the compounds of the same type. Thus, for example, a majority polymer is the polymer representing the largest mass relative to the total mass of the polymers in the composition. In the same way, a so-called majority charge is that representing the largest mass among the charges of the composition. For example, in a system comprising a single polymer, it is the majority within the meaning of the present invention; and in a system comprising two polymers, the majority polymer accounts for more than half of the mass of the polymers. In contrast, a "minor" compound is a compound that does not represent the largest mass fraction among compounds of the same type.
    [0013] In the present description, unless expressly indicated otherwise, all the percentages (%) indicated are percentages by mass. On the other hand, any range of values designated by the expression "between a and h" represents the range of values from more than a to less than b (i.e. terminals a and b excluded) while any range of values designated by the expression "from a to h" means the range from a to b (i.e., including the strict limits a and b). For the purposes of the present invention and in a manner known to those skilled in the art, tread means the layer of the tire which is in contact with the running surface. Indeed, it is possible to define within the tire three types of areas: - The inner area of the tire, that is to say that between the outer and inner zones. This zone includes layers or plies which are here called internal layers of the tire. These are, for example, carcass plies, tread sub-layers, tire belt plies or any other layer that is not in contact with the ambient air or the inflation gas of the tire. - The radially inner zone and in contact with the inflation gas, this zone being generally constituted by the inflation gas-tight layer, sometimes called inner liner ("inner liner" in English). - The radially outer zone and in contact with the ambient air, this zone consisting essentially of the tread and the outer side of the tire. The tread of the tire is disposed radially above the tire belt and thus constitutes the layer in contact with the running surface. Diene Elastomer The tire compositions of the invention may contain a single diene elastomer or a mixture of several diene elastomers.
    [0014] By elastomer (or "rubber", the two terms being considered synonymous) of the "diene" type, it will be recalled here that it is to be understood in known manner that one or more elastomers derived from at least a part (ie, a homopolymer or copolymer) of diene monomers (monomers bearing two carbon-carbon double bonds, conjugated or otherwise). The diene elastomers can be classified into two categories: "essentially unsaturated" or "essentially saturated". The term "essentially unsaturated" is generally understood to mean a diene elastomer derived at least in part from conjugated diene monomers, having a level of units or units of diene origin (conjugated dienes) which is greater than 15% (mol%); Thus, diene elastomers such as butyl rubbers or copolymers of dienes and alpha-olefins of the EPDM type do not fall within the above definition and may in particular be described as "essentially saturated" diene elastomers ( low or very low diene origin, always less than 15%). In the category of "essentially unsaturated" diene elastomers, the term "highly unsaturated" diene elastomer is particularly understood to mean a diene elastomer having a content of units of diene origin (conjugated dienes) which is greater than 50%.
    [0015] As these definitions are given, the term "diene elastomer" that can be used in the tire compositions according to the invention is more particularly understood to mean: (a) - any homopolymer obtained by polymerization of a conjugated diene monomer having from 4 to 12 carbon atoms ; (b) - any copolymer obtained by copolymerization of one or more conjugated dienes with each other or with one or more vinyl aromatic compounds having from 8 to 20 carbon atoms; (c) - a ternary copolymer obtained by copolymerization of ethylene, an α-olefin having 3 to 6 carbon atoms with a non-conjugated diene monomer having from 6 to 12 carbon atoms, for example elastomers obtained from Ethylene, propylene with a non-conjugated diene monomer of the aforementioned type such as in particular 1,4-hexadiene, ethylidene norbornene, dicyclopentadiene; (d) - a copolymer of isobutene and isoprene (butyl rubber), as well as the halogenated versions, in particular chlorinated or brominated, of this type of copolymer.
    [0016] Although it applies to any type of diene elastomer, one skilled in the art of the tire will understand that the present invention is preferably carried out with essentially unsaturated diene elastomers, in particular of the type (a) or (b). ) above.
    [0017] By way of conjugated dienes 1,3-butadiene, 2-methyl-1,3-butadiene, 2,3-di (C 1 -C 5 alkyl) -1,3-butadienes, such as, for example, 2 3-dimethyl-1,3-butadiene, 2,3-diethyl-1,3-butadiene, 2-methyl-3-ethyl-1,3-butadiene, 2-methyl-3-isopropyl-1, 3-butadiene, aryl-1,3-butadiene, 1,3-pentadiene, 2,4-hexadiene. Suitable vinylaromatic compounds are, for example, styrene, ortho-, meta-, para-methylstyrene, the "vinyl-toluene" commercial mixture, paratertiobutylstyrene, methoxystyrenes, chlorostyrenes, vinylmesitylene, divinylbenzene and vinylnaphthalene.
    [0018] The copolymers may contain between 99% and 20% by weight of diene units and between 1% and 80% by weight of vinylaromatic units. The elastomers may have any microstructure which is a function of the polymerization conditions used, in particular the presence or absence of a modifying and / or randomizing agent and the amounts of modifying and / or randomizing agent used. The elastomers can be for example block, statistical, sequence, microsequential, and be prepared in dispersion or in solution; they may be coupled and / or starred or functionalized with a coupling agent and / or starring or functionalization. For coupling with carbon black, there may be mentioned, for example, functional groups comprising a C-Sn bond or amine functional groups such as aminobenzophenone for example; for coupling to a reinforcing inorganic filler such as silica, mention may be made, for example, of silanol or polysiloxane functional groups having a silanol end (as described, for example, in FR 2,740,778, US 6,013,718 and VVO 2008/141702), alkoxysilane groups (as described for example in FR 2,765,882 or US 5,977,238), carboxylic groups (as described for example in VVO 01/92402 or US 6,815,473, VVO 2004/096865 or US 2006/0089445 ) or polyether groups (as described for example in EP 1 127 909, US 6,503,973, VVO 2009/000750 and VVO 2009/000752). As other examples of functionalized elastomers, mention may also be made of elastomers (such as SBR, BR, NR or IR) of the epoxidized type.
    [0019] These functionalized elastomers may be used in a blend with each other or with unfunctionalized elastomers. For example, a functionalized silanol or polysiloxane elastomer having a silanol end, in admixture with a coupled and / or tin-starred elastomer (described in VVO 11/042507), the latter having a rate of from 5 to 50 can be used. %, for example from 25 to 50%.
    [0020] Suitable polybutadienes and in particular those having a content (mol%) in units -1.2 of between 4% and 80% or those having a content (mol%) of cis-1,4 greater than 80%, polyisoprenes, copolymers of butadiene-styrene and in particular those having a Tg (glass transition temperature (Tg, measured according to ASTM D3418) of between 0 ° C. and -70 ° C. and more particularly between -10 ° C. and -60 ° C., a styrene content of between 5% and 60% by weight and more particularly between 20% and 50%, a content (mol%) in -1,2 bonds of the butadiene part of between 4% and 75%, a content ( mol%) in trans-1,4 bonds of between 10% and 80%, butadiene-isoprene copolymers and in particular those having an isoprene content of between 5% and 90% by weight and a Tg of -40 ° C. to At -80 ° C., the isoprene-styrene copolymers and in particular those having a styrene content of between 5% and 50% by weight and a Tg between -5 ° C and -60 ° C. In the case of butadiene-styrene-isoprene copolymers are especially suitable those having a styrene content of between 5% and 50% by weight and more particularly between 10% and 40%, a isoprene content between 15% and 60% by weight and more particularly between 20% and 50%, a butadiene content of between 5% and 50% by weight and more particularly between 20% and 40%, a content (% molar) in units -1,2 of the butadiene part of between 4% and 85%, a content (mol%) in trans-1,4 units of the butadiene part of between 6% and 80%, a content (mol% ) in units -1.2 plus -3.4 of the isoprene part of between 5% and 70% and a content (mol%) in trans units of -1.4 of the isoprenic part of between 10% and 50%, and more generally any butadiene-styrene-isoprene copolymer having a Tg between -20 ° C and -70 ° C.
    [0021] In summary, the diene elastomer of the composition is preferably chosen from the group of highly unsaturated diene elastomers consisting of polybutadienes (abbreviated as "BR"), synthetic polyisoprenes (IR) and natural rubber (NR). , butadiene copolymers, isoprene copolymers and mixtures of these elastomers. Such copolymers are more preferably selected from the group consisting of butadiene-styrene copolymers (SBR), isoprene-butadiene copolymers (BIR), isoprene-styrene copolymers (SIR), isoprene-copolymers of butadiene-styrene (SBIR), butadiene-acrylonitrile copolymers (NBR), butadiene-styrene-acrylonitrile copolymers (NSBR) or a mixture of two or more of these compounds.
    [0022] According to one particular embodiment, the composition comprises from 50 to 100 phr of an SBR elastomer, whether it be an emulsion-prepared SBR ("ESBR") or a SBR prepared in solution ("SSBR "). According to another particular embodiment, the diene elastomer is a blend (mixture) SBR / BR. According to other possible embodiments, the diene elastomer is a SBR / NR (or SBR / IR), BR / NR (or BR / IR) or SBR / BR / NR (or SBR / BR / IR) blend. ).
    [0023] In the case of an SBR elastomer (ESBR or SSBR), an SBR having an average styrene content, for example between 20% and 35% by weight, or a high styrene content, for example 35 to 35% by weight, is used in particular. 45%, a vinyl content of the butadiene part of between 15% and 70%, a content (mol%) of trans-1,4 bonds of between 15% and 75% and a Tg of between -10 ° C. and -55 ° C; such an SBR can be advantageously used in admixture with a BR preferably having more than 90% (mol%) of cis-1,4 bonds. In the case of an NBR elastomer, an NBR having an acrylonitrile content of between 15% and 40% by weight, a vinyl content of the butadiene part of between 15% and 70%, a content (% molar) in trans-1,4 bonds between 15% and 75%. According to a preferred embodiment of the invention, the rubber composition comprises a blend of one (or more) diene elastomers referred to as "high Tg" having a Tg of between -70 ° C. and 0 ° C. one (or more) diene elastomers known as "low Tg" between -110 ° C and -80 ° C, more preferably between -105 ° C and -90 ° C. The high Tg elastomer is preferably selected from the group consisting of S-SBR, E-SBR, natural rubber, synthetic polyisoprenes (having a (mol%) content of cis-1,4 linkages of preferably greater than 95%), BIRs, SIRs, SBIRs, and mixtures of these elastomers.
    [0024] The low Tg elastomer preferably comprises butadiene units at a level (mol%) of at least 70%; it consists preferably of a polybutadiene (BR) having a content (mol%) of cis-1,4 chains greater than 90%. According to another particular embodiment of the invention, the rubber composition comprises, for example, between 30 and 90 phr, in particular between 40 and 90 phr, of a high Tg elastomer in a blend with a low Tg elastomer. Another particular embodiment of the invention, the diene elastomer of the composition according to the invention comprises a blend of a BR (as low elastomer Tg) having a rate (% molar) of cis-chains. 1.4 greater than 90%, with one or more S-SBR or E-SBR (as elastomer (s) high Tg). 1-2 Polyfunctional Acrylate Derivative The tire according to the invention comprises a composition which comprises a polyfunctional acrylate derivative of formula (Ia) or (Ib) R 1, R 3, R 3 Wherein R1, R2 and R3 independently represent a hydrogen atom or a C1-07 hydrocarbon group selected from the group consisting of linear, branched or cyclic alkyls, aralkyl groups, groups; alkylaryls and aryl groups, and optionally interrupted by one or more heteroatoms, R2 and R3 may together form a non-aromatic ring, n represents an integer of value 1, 2 or 3, and in the case of an acrylate derivative polyfunctional of formula (Ia), R4 represents a radical selected from the group consisting of a hydrogen atom, a methyl group, an ethyl group, a propyl group or an isopropyl group. By cyclic alkyl group is meant an alkyl group comprising one or more rings.
    [0025] By group or hydrocarbon chain (e) interrupted by one or more heteroatoms is meant a group or chain comprising one or more heteroatoms, each heteroatom being between two carbon atoms of said group or said chain, or between an atom carbon of said group or said chain and another heteroatom of said group or said chain or between two other hetero atoms of said group or said chain. The heteroatom (s) may be a nitrogen, sulfur or oxygen atom.
    [0026] Preferably in formulas (Ia) and (Ib) above, R1, R2 and R3 independently represent a hydrogen atom or a methyl group. More preferably, R 2 and R 3 each represent a hydrogen atom and according to a very preferred alternative R 1 represents a methyl group. Preferably, n is 1 in formulas (Ia) and (Ib) above.
    [0027] Preferentially, in the case of a polyfunctional acrylate derivative of formula (Ia), R4 represents an ethyl group. In the tire composition according to the invention, the amount of polyfunctional acrylate derivative is preferably in a range from 10 to 70 phr, preferably from 10 to 60 phr. Beyond a rate of 70 phr, the dispersion is less good and the properties of the composition may be degraded while below a level of 10 phr, the effect of the polyfunctional acrylate derivative is less significant on stiffening and reinforcement.
    [0028] By way of example, there are commercially available polyfunctional acrylate derivatives such as trimethylolpropane trimethacrylate (TMPTMA) "SR351" from the company SARTOM ER. 1-3 Peroxide In addition to the above-described diene elastomer and polyfunctional acrylate derivative, the tire composition of the invention utilizes a peroxide, which may be any peroxide known to those skilled in the art.
    [0029] Among the peroxides, which are well known to those skilled in the art, it is preferable to use, for the invention, a peroxide chosen from the family of organic peroxides, and in particular a peroxide chosen from dicumyl peroxide, peroxides of d aryl or diaryl, diacetyl peroxide, benzoyl peroxide, dibenzoyl peroxide, ditertbutyl peroxide, tertbutylcumyl peroxide, 2,5-bis (tertbutylperoxy) -2,5-dimethylhexane, and mixtures thereof. of these. There are various packaged products commercially known under their trademarks; we can mention: -the "Dicup" of the company Hercules Powder Co., the "Perkadox Y12" of the Noury van der Lande Company, the "Peroximon F40" of the company Montecatini Edison SpA, the "Trigonox" of the Noury Company van der Lande, the "Varox" of RTVanderbilt Co., or the "Luperko" from Wallace & Tiernan, Inc. Preferably, the amount of peroxide to be used for the purposes of the invention is less than or equal to 3 phr. Preferably, the amount of peroxide in the composition is in a range from 0.1 to 3 phr. Indeed, below an amount of 0.1 phr, the effect of the peroxide is not noticeable whereas beyond 3 phr, the properties of elongation rupture and therefore resistance of the composition are decreased . More preferably, the amount of peroxide in the composition is in a range from 0.2 to 2 phr, preferably from 0.25 to 1 phr. Regardless of the amounts of polyfunctional acrylate derivative and peroxide seen above, it is important for the invention that the ratio of the polyfunctional acrylate derivative level to the peroxide level be greater than or equal to 6. below, of such a ratio of the rates the synergy between the polyfunctional acrylate derivative and the peroxide is not as efficient in terms of the effect on the rheometry and the elongation rupture, in particular for a composition subject to constraints of a tire.
    [0030] Preferably, the ratio of the level of polyfunctional acrylate derivative to the level of peroxide is greater than or equal to 7, preferably greater than or equal to 8 and more preferably greater than or equal to 10. More preferably, the ratio of the level of derivative of polyfunctional acrylate on the peroxide content is between 10 and 110, preferably between 10 and 70, and more preferably between 10 and 40. 1-4 Reinforcing filler The tire composition according to the invention also comprises a reinforcing filler .
    [0031] The physical state under which the reinforcing filler is present is indifferent, whether in the form of powder, microbeads, granules, beads or any other suitable densified form.
    [0032] Any type of reinforcing filler known for its ability to reinforce a rubber composition usable for the manufacture of tires may be used, for example an organic filler such as carbon black, a reinforcing inorganic filler such as silica, or a cut of these two types of load. Carbon blacks are suitable for all carbon blacks, especially so-called pneumatic grade blacks. Among these, the reinforcing carbon blacks of the 100, 200 or 300 series (ASTM grades), for example the N115, N134, N234, N326, N330, N339, N347 or N375 blacks, or even targeted applications, blacks of higher series (eg N660, N683, N772). The carbon blacks could for example already be incorporated into an isoprene elastomer in the form of a masterbatch (see for example applications VVO 97/36724 or VVO 99/16600). Examples of organic fillers other than carbon blacks include organic functionalized polyvinyl fillers as described in applications VVO-A-2006/069792, VVO-A-2006/069793, VVO-A-2008 / 003434 and VVO-A2008 / 003435. The composition may also contain a type of silica or a blend of several silicas. The silica used may be any reinforcing silica known to those skilled in the art, in particular any precipitated or fumed silica having a BET surface and a CTAB specific surface both less than 450 m 2 / g, preferably from 30 to 400 m 2 /boy Wut. As highly dispersible precipitated silicas (referred to as "HDS"), mention may be made, for example, of the "Ultrasil 7000" and "Ultrasil 7005" silicas of Degussa, the "Zeosil" silicas 1165MP, 1135MP and 1115MP of Rhodia, "Hi-Sil EZ150G" silica from PPG, the "Zeopol" silicas 8715, 8745 and 8755 from Huber, processed precipitated silicas such as, for example, the "aluminum doped" silicas described in EP application -A-0735088 or silicas with high specific surface area as described in application VVO 03/16837. The silica preferably has a BET surface area of between 45 and 400 m 2 / g, more preferably between 60 and 300 m 2 / g. Those skilled in the art will understand that, as the equivalent filler of the silica described in this paragraph, it would be possible to use a reinforcing filler of another nature, in particular an organic one, since this reinforcing filler would be covered with a layer silica, or would comprise on its surface functional sites, including hydroxyl, requiring the use of a coupling agent to establish the bond between the filler and the elastomer. The volume fraction of reinforcing filler in the rubber composition is defined as the ratio of the volume of the reinforcing filler to the volume of all the constituents of the composition, it being understood that the volume of all the constituents is calculated in adding the volume of each of the constituents of the composition. The volume fraction of reinforcing filler in a composition is therefore defined as the ratio of the volume of the reinforcing filler to the sum of the volumes of each of the constituents of the composition, and preferably this volume fraction is between 5% and 20%. preferably between 5% and 15%. In a preferentially equivalent manner, the total reinforcing filler content (carbon black and / or silica) is less than 50 phr, preferably 5 to 45 phr, more preferably 10 to 40 phr, and very preferably from 15 to 35 phr. Indeed, an advantage of the invention is to reduce the rate of reinforcing filler without losing performance. Beyond a rate of 50 phr, this advantage is not as great and the hysteresis of the composition increases.
    [0033] Thus, preferably, the ratio of the charge ratio and the level of polyfunctional acrylate derivative is less than or equal to 3.5; preferably, less than or equal to 3. More preferably, this ratio is in a range from 0.3 to 3, preferably from 1 to 3.
    [0034] Preferably, the tire composition according to the invention comprises predominantly carbon black as a reinforcing filler. Alternatively and preferably also, the tire composition according to the invention comprises silica predominantly as a reinforcing filler. By majority reinforcing filler is meant that which has the highest rate among the reinforcing fillers present in the composition. In particular, the term "majority reinforcing filler" means any reinforcing filler which represents at least 50% by weight of the reinforcing fillers present, preferably more than 50% and more preferably more than 60%.
    [0035] These compositions may optionally also contain, in addition to reinforcing fillers, and in particular when silica is used in the tire composition according to the invention, coupling agents, coupling activators, charge-covering agents. inorganic agents or, more generally, processing aids which, in a known manner, by improving the dispersion of the filler in the rubber matrix and lowering the viscosity of the compositions, improve their ability to in the green state, these agents being, for example, hydrolysable silanes such as alkylalkoxysilanes, polyols, fatty acids, polyethers, primary, secondary or tertiary amines, hydroxylated or hydrolysable polyorganosiloxanes. As coupling agent, polysulphurized silanes, called "symmetrical" or "asymmetrical" silanes according to their particular structure, are used, as described, for example, in the applications W003 / 002648 (or US 2005/016651) and W003 / 002649. (or US 2005/016650). In particular, polysulphide silanes known as "symmetrical" silanes having the following general formula (III) are suitable, but not limited to: (III) Z - A - Sx - A - Z, in which: - x is an integer of 2 to 8 (preferably 2 to 5); A is a divalent hydrocarbon radical (preferably C 1 -C 18 alkylene groups or C 8 -C 12 arylene groups, more particularly C 1 -C 10 alkylenes, especially C 1 -C 4 alkylenes, in particular propylene); Z corresponds to one of the following formulas: ## STR2 ## in which: the radicals R 1, substituted or unsubstituted, identical or different from one another; represent a C 1 -C 18 alkyl, C 5 -C 18 cycloalkyl or C 8 -C 18 aryl group (preferably C 1 -C 8 alkyl, cyclohexyl or phenyl groups, especially C 1 -C 4 alkyl groups, more particularly methyl and / or ethyl). the radicals R2, substituted or unsubstituted, which are identical to or different from each other, represent a C1-C18 alkoxyl or a C5-C18 cycloalkoxyl group (preferably a group chosen from C1-C8 alkoxyls and C5-C08 cycloalkoxyls); still more preferably a group chosen from C 1-4 alkoxyls, in particular methoxyl and ethoxyl). In the case of a mixture of polysulfide alkoxysilanes corresponding to the formula (II) above, in particular common commercially available mixtures, the average value of the "x" is a fractional number preferably between 2 and 5, more preferably close to 4. But the invention can also be advantageously used for example with disulfide alkoxysilanes (x = 2). As examples of polysulfide silanes, mention may be made more particularly of polysulfides (especially disulfides, trisulphides or tetrasulfides) of bis- (alkoxyl (01-04) -alkyl (Ci-C4) silyl-alkyl (C1-C4)), as for example polysulfides of bis (3-trimethoxysilylpropyl) or bis (3-triethoxysilylpropyl). Among these compounds, bis (3-triethoxysilylpropyl) tetrasulfide, abbreviated TESPT, of formula [(02H50) 3Si (OH2) 3S1 or bis (triethoxysilylpropyl) disulfide, abbreviated TESPD, of formula (2:50) 3 Si (0H2) 3SK. Mention may also be made, by way of preferred examples, of polysulfides (in particular disulphides, trisulphides or tetrasulfides) of bis (monoalkoxyl (01-04) -dialkyl (01-04) silylpropyl), more particularly bis-monoethoxydimethylsilylpropyl tetrasulfide, as described in US Pat. patent application VVO 02/083782 (or US 2004/132880).
    [0036] As coupling agent other than polysulfide alkoxysilane, mention may also be made of bifunctional POS (polyorganosiloxanes) or hydroxysilane polysulfides (R2 = OH in formula III above) as described in the patent applications VVO 02/30939 (or US Pat. No. 6,774,255) and VVO 02/31041 (or US 2004/051210), or also silanes or POS bearing azo-dicarbonyl functional groups, as described, for example, in patent applications VVO 2006/125532, VVO 2006/125533, VVO 2006/125534. In the rubber compositions useful in the invention, the content of coupling agent is preferably between 1 and 5 phr, more preferably between 1 and 4 and even more preferably between 1 and 3.5 phr. The vulcanization system The tire composition according to the invention does not require a vulcanization system, which is one of its advantages since it makes it possible to simplify the formula and the preparation of the composition. If, however, a vulcanization system is present in the composition, it is preferably in low amounts explained below.
    [0037] The vulcanization system itself is usually based on sulfur (or a sulfur-donor agent) and a primary vulcanization accelerator. To this basic vulcanization system are added, incorporated during the first non-productive phase and / or during the production phase as described later, various known secondary accelerators or vulcanization activators such as zinc oxide. stearic acid or equivalent compounds, guanidine derivatives (in particular diphenylguanidine). The molecular sulfur (or equivalently the molecular sulfur donor agents), when it is used, is at a level preferably less than 0.5 phr, preferably less than 0.3 phr, more preferably at a rate less than 0.1 phr. Most preferably, the composition is free of molecular sulfur. The vulcanization system of the composition according to the invention may also comprise one or more additional accelerators, for example the compounds of the thiuram family, the zinc dithiocarbamate derivatives, the sulphenamides, the guanidines or the thiophosphates. In particular, any compound capable of acting as a vulcanization accelerator for diene elastomers in the presence of sulfur, in particular thiazole type accelerators and their derivatives, thiuram type accelerators, zinc dithiocarbamates, may be used in particular. These accelerators are more preferably selected from the group consisting of 2-mercaptobenzothiazyl disulfide (abbreviated as "M BTS"), N-cyclohexyl-2-benzothiazyl sulfenamide (abbreviated "CBS"), N, N-dicyclohexyl benzothiazyl sulphenamide (abbreviated "DCBS"), N-tert-butyl-2-benzothiazyl sulphenamide (abbreviated "TBBS"), N-tert-butyl-2-benzothiazyl sulphenimide (abbreviated "TBSI"), zinc dibenzyldithiocarbamate ( abbreviated "ZBEC") and mixtures of these compounds. Preferably, a primary accelerator of the sulfenamide type is used. If an accelerator is used, it is at rates such as those practiced by those skilled in the art of vulcanized tire compositions. Nevertheless, the tire composition according to the invention is preferably devoid of any vulcanization accelerator. 1-6 Other Possible Additives The tire compositions according to the invention optionally also include all or part of the usual additives usually used in elastomer compositions intended in particular for the production of treads, such as, for example, pigments, agents and the like. such as anti-ozone waxes, chemical anti-ozonants, anti-oxidants, plasticizers such as those proposed below, anti-fatigue agents, reinforcing resins, acceptors (for example phenolic novolac resin) or methylene donors (eg HMT or H3M). According to a preferred embodiment, the tire composition of the invention is devoid of antioxidant.
    [0038] According to a preferred embodiment, the tire composition of the invention is devoid of plasticizer. Alternatively and according to a also preferred embodiment, the composition according to the invention further comprises a plasticizer. Preferably this plasticizer is a solid hydrocarbon resin (or plasticizing resin), an extender oil (or plasticizing oil), or a mixture of both. When it is included in the composition, the level of total plasticizer is preferably greater than or equal to 5 phr, more preferably 5 to 100 phr, in particular 10 to 80 phr, for example 15 to 70 phr. According to a first preferred embodiment of the invention, the plasticizer is a liquid extension oil at 20 ° C, said to "low Tg", that is to say that by definition has a Tg lower than -20 ° C, preferably below -40 ° C.
    [0039] Any extender oil, whether of aromatic or non-aromatic nature known for its plasticizing properties vis-à-vis diene elastomers, is usable. At ambient temperature (20 ° C), these oils, more or less viscous, are liquids (that is to say, as a reminder, substances having the ability to eventually take the shape of their container), as opposed in particular to hydrocarbon plasticizing resins which are inherently solid at room temperature. Particularly suitable extension oils selected from the group consisting of naphthenic oils (low or high viscosity, including hydrogenated or not), paraffinic oils, oils MES (Medium Extracted Solvates), oils TDAE (Treated Distillate Aromatic Extracts) ), mineral oils, vegetable oils, ethers plasticizers, ester plasticizers, phosphate plasticizers, sulphonate plasticizers and mixtures of these compounds. For example, there may be mentioned those containing between 12 and 30 carbon atoms, for example trioctyl phosphate. By way of examples of non-aqueous and non-water-soluble ester plasticizers, mention may be made in particular of compounds selected from the group consisting of trimellitates, pyromellitates, phthalates, 1,2-cyclohexane dicarboxylates, adipates, azela- sebacates, glycerol triesters and mixtures of these compounds. Among the triesters above, mention may be made in particular of glycerol triesters, preferably consisting mainly (for more than 50%, more preferably for more than 80% by weight) of a C18 unsaturated fatty acid, that is, that is to say chosen from the group consisting of oleic acid, linoleic acid, linolenic acid and mixtures of these acids. More preferably, whether of synthetic or natural origin (for example vegetable oils of sunflower or rapeseed), the fatty acid used is more than 50% by weight, more preferably still more than 80% by weight. % by weight of oleic acid. Such high oleic acid triesters (trioleates) are well known and have been described, for example, in application VVO 02/088238, as plasticizers in tire treads.
    [0040] According to another preferred embodiment of the invention, this plasticizer is a thermoplastic hydrocarbon resin whose Tg is greater than 0 ° C, preferably greater than 20 ° C. This resin is a solid at room temperature (23 ° C), as opposed to a liquid plasticizer such as an oil.
    [0041] Preferably, the thermoplastic hydrocarbon plasticizing resin has at least one of the following characteristics: a Tg greater than 20 ° C, more preferably greater than 30 ° C; a number-average molecular mass (Mn) of between 400 and 2000 g / mol, more preferentially between 500 and 1500 g / mol; a polymolecularity index (Ip) of less than 3, more preferably less than 2 (booster: lp = Mw / Mn with Mw weight average molecular weight). More preferably, this thermoplastic hydrocarbon plasticizing resin has all of the above preferred characteristics. The macrostructure (Mw, Mn and lp) of the hydrocarbon resin is determined by steric exclusion chromatography (SEC): solvent tetrahydrofuran; temperature 35 ° C; concentration 1 g / I; flow rate 1 ml / min; filtered solution on 0.45 μm porosity filter before injection; Moore calibration with polystyrene standards; set of 3 "WATERS" columns in series ("STYRAGEL" HR4E, HR1 and HR0.5); differential refractometer detection ("WATERS 2410") and its associated operating software ("WATERS EMPOVVER"). The thermoplastic hydrocarbon resins may be aliphatic or aromatic or alternatively of the aliphatic / aromatic type, that is to say based on aliphatic and / or aromatic monomers. They may be natural or synthetic, whether or not based on petroleum (if so, also known as petroleum resins). Examples of suitable aromatic monomers are styrene, alphamethylstyrene, ortho-, meta-, para-methylstyrene, vinyl-toluene, para-tert-butylstyrene, methoxystyrenes, chlorostyrenes, vinylmesitylene, divinylbenzene, vinylnaphthalene, any vinylaromatic monomer resulting from a Cg cut (or more generally from a Cg to C10 cut). Preferably, the vinylaromatic monomer is styrene or a vinylaromatic monomer derived from a Cg cut (or more generally from a C8 to C10 cut). Preferably, the vinylaromatic monomer is the minor monomer, expressed as a mole fraction, in the copolymer under consideration. According to a particularly preferred embodiment, the plasticizing hydrocarbon resin is selected from the group consisting of homopolymer resins or copolymers of cyclopentadiene (abbreviated CPD) or dicyclopentadiene (abbreviated DCPD), terpene homopolymer or copolymer resins, terpene phenol homopolymer or copolymer resins, homopolymer or cutting copolymer resins 05, homopolymer or cutting copolymer resins 09, alpha-methyl-styrene homopolymer and copolymer resins, and mixtures of these resins, which may be used alone or in combination with a liquid plasticizer, for example a MES or TDAE oil. The term "terpene" here combines in a known manner the alpha-pinene, beta-pinene and limonene monomers; preferably, a limonene monomer is used which is present in a known manner in the form of three possible isomers: L-limonene (laevorotatory enantiomer), D-limonene (dextrorotatory enantiomer), or the dipentene, racemic of the dextrorotatory and levorotatory enantiomers. . Among the above-mentioned hydrocarbon plasticizing resins, there may be mentioned resins of homo- or copolymers of alphapinene, betapinene, dipentene or polylimonene. The preferred resins above are well known to those skilled in the art and commercially available, for example sold with regard to: - polylimonene resins: by the company DRT under the name "Dercolyte L120" (Mn = 625 g / mol Mw = 1010 g / mol, Ip = 1.6, Tg = 72 ° C.) or by ARIZONA under the name "Sylvagum TR71250" (Mn = 630 g / mol, Mw = 950 g / mol, Ip = 1 5, Tg = 70 ° C); - 05 / vinylaromatic copolymer resins, in particular cut 05 / styrene or cut 05 / cut Cg: by Neville Chemical Company under the names "Super Nevtac 78", "Super Nevtac 85" or "Super Nevtac 99", by Goodyear Chemicals under "VVingtack Extra" denomination, by Kolon under the names "Hikorez T1095" and "Hikorez T1100", by Exxon under the names "Escorez 2101" and "Escorez 1273"; limonene / styrene copolymer resins: by DRT under the name "Dercolyte TS 105" from the company DRT, by ARIZONA Chemical Company under the names "ZT115LT" and "ZT5100".
    [0042] As examples of other preferred resins, mention may also be made of phenol-modified alpha-methyl-styrene resins. To characterize these phenol-modified resins, it is recalled that a so-called "hydroxyl number" index (measured according to ISO 4326 and expressed in mg KOH / g) is used in a known manner. The alpha-methylstyrene resins, in particular those modified phenol, are well known to those skilled in the art and commercially available, for example sold by the company Arizona-Chemical under the names "Sylvares SA 100" (Mn = 660 g / mol lp = 1.5, Tg = 53 ° C); "Sylvares SA 120" (Mn = 1030 g / mol, lp = 1.9, Tg = 64 ° C); "Sylvares 540" (Mn = 620 g / mol, lp = 1.3, Tg = 36 ° C, hydroxyl number = 56 mg KOH / g); "Silvares 600" (Mn = 850 g / mol, lp = 1.4, Tg = 50 ° C, hydroxyl number = 31 mg KOH / g). It goes without saying that the invention relates to tires provided with treads comprising the rubber compositions described above both in the so-called "raw" or uncrosslinked state (ie, before cooking) that said state "cooked "or crosslinked, or vulcanized (ie, after crosslinking or vulcanization). II-Preparation of Rubber Compositions The compositions are manufactured in suitable mixers, using two successive preparation phases well known to those skilled in the art: a first working phase or thermomechanical mixing (sometimes referred to as a "no" phase). - productive ") at high temperature, up to a maximum temperature between 110 ° C and 190 ° C, preferably between 130 ° C and 180 ° C, followed by a second phase of mechanical work (sometimes called phase" Producer ") at a lower temperature, typically below 110 ° C, for example between 60 ° C and 100 ° C, finishing phase during which is incorporated the crosslinking or vulcanization system and in particular the peroxide of the compositions according to the present invention. 'invention; such phases have been described for example in the applications EP-A-0501227, EP-A-0735088, EP-A0810258, W000 / 05300 or W000 / 05301. The first (non-productive) phase is preferably carried out in several thermomechanical steps. In a first step, the elastomers and the reinforcing fillers (and optionally the coupling agents and / or other ingredients) are introduced into a suitable mixer such as a conventional internal mixer at a temperature of between 20.degree. ° C and 100 ° C and preferably between 25 ° C and 100 ° C. After a few minutes, preferably from 0.5 to 2 min and a rise in temperature at 90 ° C to 100 ° C, the remaining ingredients (i.e., those remaining if all were not initially) are added at once or in portions, with the exception of the crosslinking system and in particular the peroxide during a mixing ranging from 20 seconds to a few minutes. The total mixing time, in this non-productive phase, is preferably between 2 and 10 minutes at a temperature of less than or equal to 180 ° C, and preferably less than or equal to 170 ° C. After cooling the mixture thus obtained, the crosslinking system and in particular the peroxide are then incorporated at low temperature (typically below 100 ° C.), generally in an external mixer such as a roller mixer; the whole is then mixed (productive phase) for a few minutes, for example between 5 and 15 min. The final composition thus obtained is then calendered, for example in the form of a sheet or a plate, in particular for a characterization in the laboratory, or extruded, to form for example a rubber profile used for the manufacture of semi-finished products. finished in order to obtain products such as sidewalls, carcass ply, crown plies (or tire belt), tread, bead filler, tread underlayer or other layers of elastomers, preferentially the rolling. These products can then be used for the manufacture of tires, according to the techniques known to those skilled in the art. The crosslinking (or baking) is conducted in a known manner at a temperature generally between 130 ° C and 200 ° C, under pressure, for a sufficient time which may vary for example between 5 and 90 min depending in particular on the cooking temperature , the crosslinking system adopted, the kinetics of crosslinking of the composition in question or the size of the tire. The following examples illustrate the invention without limiting it.
    [0043] The compositions as described in the present application may be used anywhere in the tire, and preferably in its tread or in an inner layer of this tire. Indeed, it is possible to define within the tire three types of areas: - The radially outer zone and in contact with the ambient air, this zone consisting essentially of the tread and the outer side of the tire. - The radially inner zone and in contact with the inflation gas, this zone being generally constituted by the inflation gas-tight layer, sometimes called inner liner ("inner liner" in English). - The inner area of the tire, that is to say that between the outer and inner zones. This zone includes layers or webs which are here called internal layers of tires. These are, for example, carcass plies, tread sub-layers, tire belt plies or any other layer that is not in contact with the ambient air or the inflation gas of the tire. III-Examples of embodiment of the invention III-1 Preparation of the examples In the examples which follow, the rubber compositions were produced as described previously. III-2 Characterization of the Examples In the examples, the rubber compositions are characterized before and / or after cooking as indicated below. Dynamic properties (after firing): Tensile test These tensile tests make it possible to determine the elastic stresses and the properties at break. Unless otherwise indicated, they are carried out in accordance with the French standard NF T 46-002 of September 1988. Traction data processing also makes it possible to plot the modulus curve as a function of elongation. The module used here is the nominal secant modulus (or apparent) measured in first elongation, calculated by reducing to the initial section of the specimen. The nominal secant moduli (or apparent stresses, in MPa) are measured at first elongation at 50%, 100% and 300% elongation respectively denoted M50, M100 and M300.
    [0044] The breaking stresses (in MPa) and the elongations at break (AR in%) are also measured at 23 ° C. ± 2 ° C., according to standard NF T 46-002. The results are expressed "in base 100" that is to say compared to the witness to which a value 100 is attributed. 15 - 27 - All these tensile measurements are carried out under the normal conditions of temperature (23 ± 2 ° C) and humidity (50 ± 5% relative humidity), according to the French standard NF T 40-101 (December 1979). The dynamic properties G * (10%) and tan (8) max at 40 ° C are measured on a viscoanalyzer (Metravib VA4000) according to ASTM D 5992-96. The response of a sample of vulcanized composition (cylindrical specimen 4 mm thick and 400 mm 2 in section), subjected to a sinusoidal stress in alternating simple shear, at the frequency of 10 Hz, under the defined temperature conditions, is recorded. for example at 40 ° C according to ASTM D 1349-99, or as the case may be at a different temperature. A strain amplitude sweep of 0.1 to 50% (forward cycle) and then 50% to 1% (return cycle) are performed. The results exploited are the complex dynamic shear modulus G * and the loss factor tan (). For the return cycle, the maximum value of tan (δ) observed, denoted tan (δ) max, as well as the complex dynamic shear modulus G * (10%) at 10% deformation, at 40 ° C. are indicated. It is recalled that, in a manner well known to those skilled in the art, the value of tan (8) max at 40 ° C. is representative of the hysteresis of the material and thus of the rolling resistance: plus tan (8) max at 40 ° C. ° C is low, the lower the rolling resistance.
    [0045] III-3 Examples III-3-1 Example I The purpose of this example is to compare the rubber properties of control compositions with compositions according to the invention, loaded with carbon black. The compositions tested are presented in Table 1 below. Table 1 Ti T2 T3 T4 T5 T6 Cl C2 NR (1) 100 100 100 100 100 100 100 100 Black (2) 50 50 0 20 40 0 20 40 TMPTMA (3) - 5 - - - 17 17 17 Peroxide (4) - 3 1.5 1.5 1.5 1.5 1.5 1.5 TMPTMA / Peroxide - 1.7 - - - 11.3 11.3 11.3 Filler / TMPTMA - 10.0 - - - 0,0 1,2 2,4 Stearic acid (5) 0,5 0,5 0,5 0,5 0,5 0,5 0,5 0,5 ZnO (6) 7 7 7 7 7 7 7 7 6-PPD (7) 1,5 - - - - - - - Accelerator (8) 0,8 - - - - - - - Sulfur 4,5 - - - - - - - (1) Natural Rubber ( 2) Carbon black grade ASTM N326 from Cabot (3) Trimethylolpropane trimethacrylate (TMPTMA) "SR351" from SARTOMER (4) Dicumyl peroxide "Dicup" from Hercules (5) Stearin "Pristerene 4931" from the Uniqema company (6) Zinc oxide industrial grade - company Umicore (7) N- (1,3-dimethylbutyl) -N'-phenyl-p-phenylenediamine "Santoflex 6-PPD" from Flexsys (8) N-dicyclohexyl 2-Benzothiazol sulfenamide "Santocure DCBS" from the company Flexsys Table 2 below gives e the properties measured for the different compositions. Table 2 Tl T2 T3 T4 T5 T6 Cl C2 AR (%) 480 200 380 310 305 210 330 320 M300 11/2 6 11/11 14.5 Tg (delta) max at 40 ° C 0.19 0.18 0, 06 0.11 0.15 0.07 0.13 0.16 Compared to the control compositions, it is noted that the composition C1 is at the same level of reinforcement (represented by M300) as the control compositions Ti and T5 but with a greatly diminished hysteresis. The composition 03 makes it possible to achieve a high level of reinforcement (M300) while maintaining a low hysteresis and a good cohesion (represented by the elongation rupture). III-3-2 Example II This example is intended to compare the rubber properties of control compositions to compositions in accordance with the invention, loaded with silica. The compositions tested are shown in Table 3 below. Table 3 T7 T8 T9 T10 T11 C3 C4 NR (1) 100 100 100 100 100 100 100 Silica (2) 50 0 20 40 0 20 40 TMPTMA (3) 5 - - - 17 17 17 Peroxide (4) 3 1.5 1.5 1.5 1.5 1.5 1.5 TMPTMA / Peroxide 1.7 - - - 11.3 11.3 11.3 Filler / TMPTMA 10.0 - - - 0.0 1.2 2, Stearic acid (5) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 ZnO (6) 7 7 7 7 7 7 7 Coupling agent (7) 4 - 1.6 3, 2 - 1.6 3.2 (1) Natural Rubber (2) Silica 160 MP, "Zeosil 1165MP" from Rhodia (3) Trimethylolpropane trimethacrylate (TMPTMA) "5R351" from Sartomer (4) Dicumyl peroxide " Dicup "from Hercules (5) Stearin" Pristerene 4931 "from Uniqema (6) Zinc oxide industrial grade - Umicore company (7) TESPT coupling agent" 5i69 "from Evonik Company Table 4 below gives the properties measured for the different compositions. - 30 - Table 4 T7 T8 T9 T10 T11 C3 C4 AR (%) 230 390 320 310 200 400 460 M300 / 1.3 3.5 6/9 13.5 Tg (delta) max at 40 ° C 0.17 0 0.07 0.09 0.05 0.07 0.18 Compared with the control compositions, it is noted that the compositions 03 and 04 make it possible to achieve a strong reinforcement (M300) with a low hysteresis and to maintain good cohesion (breaking elongation).
    权利要求:
    Claims (31)
    [0001]
    REVENDICATIONS1. A tire comprising a rubber composition based on at least one diene elastomer, a reinforcing filler, a polyfunctional acrylate derivative of the formula (Ia) or (Ib) wherein R1, R2 and R3 independently represent a hydrogen atom or a C1-C7 hydrocarbon group selected from the group consisting of linear, branched or cyclic alkyls, aralkyl groups, alkylaryl groups and aryl groups, and optionally interrupted by one or more heteroatoms, R2 and R3 may together form a ring non-aromatic, n represents an integer of value 1, 2 or 3, and in the case of a polyfunctional acrylate derivative of formula (Ia), R 4 represents a radical chosen from the group consisting of a hydrogen atom, a methyl group, an ethyl group, a propyl group or an isopropyl group, the said composition also comprising a peroxide, the levels of acrylate derivative wherein R1 R3 / R2 R2 R1 (la) Wherein the ratio of polyfunctional acrylate derivative level to peroxide level is greater than or equal to 6.
    [0002]
    2. A tire according to claim 1, wherein R1, R2 and R3 independently represent a hydrogen atom or a methyl group.
    [0003]
    3. A tire according to any one of the preceding claims, wherein R2 and R3 each represent a hydrogen atom.
    [0004]
    4. A tire according to any one of the preceding claims, wherein R 1 represents a methyl group.
    [0005]
    A tire according to any one of the preceding claims, wherein n is the integer 1.
    [0006]
    A tire according to any one of the preceding claims, wherein the polyfunctional acrylate derivative is a compound of formula (Ia).
    [0007]
    Pneumatic tire according to claim 6, wherein R4 represents an ethyl group.
    [0008]
    The tire of any one of claims 1 to 5, wherein the polyfunctional acrylate derivative is a compound of formula (Ib).
    [0009]
    A tire according to any one of the preceding claims, wherein the amount of polyfunctional acrylate derivative in the composition is within a range of from 10 to 70 phr (parts by weight per hundred parts by weight of elastomer), preferably from 10 to 60 phr.
    [0010]
    A tire according to any one of the preceding claims, wherein the peroxide in the composition is an organic peroxide.
    [0011]
    11. A tire according to any one of the preceding claims, wherein the amount of peroxide in the composition is less than or equal to 3 phr.
    [0012]
    Tire according to any one of the preceding claims, wherein the amount of peroxide in the composition is within a range of from 0.1 to 3 phr.
    [0013]
    13. A tire according to any one of the preceding claims, wherein the amount of peroxide in the composition is in a range from 0.2 to 2 phr, preferably from 0.25 to 1 phr.
    [0014]
    14. A tire according to any one of the preceding claims, wherein the ratio of the polyfunctional acrylate derivative level to the peroxide level is greater than or equal to 7, preferably greater than or equal to 8 and more preferably greater than or equal to 10.
    [0015]
    Tire according to the preceding claim, in which the ratio of the level of polyfunctional acrylate derivative to the peroxide content is between 10 and 110, preferably between 10 and 70, and more preferably between 10 and 40.
    [0016]
    A tire according to any one of the preceding claims wherein the diene elastomer is selected from the group consisting of polybutadienes, synthetic polyisoprenes, natural rubber, butadiene copolymers, isoprene copolymers and these elastomers. 20
    [0017]
    A tire according to claim 16 wherein the diene elastomer is selected from the group consisting of polybutadienes, synthetic polyisoprenes, natural rubber, butadiene and styrene copolymers, butadiene and acrylonitrile copolymers, copolymers of isoprene and styrene and mixtures of these elastomers. 25
    [0018]
    18. A tire according to any one of the preceding claims, wherein the composition comprises less than 50 phr of reinforcing filler.
    [0019]
    19. A tire according to claim 18, wherein the reinforcing filler content is in a range from 5 to 45 phr.
    [0020]
    20. The tire of claim 19, wherein the reinforcing filler content is in a range from 10 to 40 phr, preferably from 15 to 35 phr. 35
    [0021]
    21. A tire according to any one of the preceding claims wherein the reinforcing filler is carbon black, silica or a mixture thereof. 10- 34 -
    [0022]
    22. A tire according to claim 21 wherein the reinforcing filler is predominantly made of carbon black.
    [0023]
    23. A tire according to claim 21 wherein the reinforcing filler consists mainly of silica.
    [0024]
    24. A tire according to any one of the preceding claims wherein the ratio of the charge ratio and the level of polyfunctional acrylate derivative is less than or equal to 3.5; preferably less than or equal to 3.
    [0025]
    25. Tire according to the preceding claim wherein the ratio of the charge ratio and the level of polyfunctional acrylate derivative is in a range from 0.3 to 3; preferably from 1 to 3.
    [0026]
    A tire according to any one of the preceding claims wherein the composition does not contain molecular sulfur or sulfur donor agent as a vulcanizing agent or contains less than 0.5 phr.
    [0027]
    27. A tire according to any one of the preceding claims wherein the composition does not contain molecular sulfur or sulfur donor agent as vulcanizer or contains less than 0.3 phr and preferably less than 0. , 1 pce.
    [0028]
    28. A tire according to any one of the preceding claims wherein the composition does not contain a vulcanization accelerator.
    [0029]
    29. A tire according to any one of the preceding claims wherein the composition does not contain an antioxidant.
    [0030]
    30. The tire according to claim 1, wherein the composition further comprises a plasticizer, preferably chosen from plasticizing resins, extension oils and mixtures thereof.
    [0031]
    31. Tire according to one of the preceding claims wherein the composition as specified in claims 1 to 30 is that of the tread, or an inner layer of said tire.
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    EP3328933B1|2019-09-04|Rubber composition comprising hydrocarbon resin having low glass transition temperature
    EP3317345B1|2019-08-07|Rubber composition comprising hydrocarbon resin having low glass transition temperature, coupling agent and primary amine
    EP2794748B1|2018-06-27|Tyre comprising a composition essentially free of guanidine derivatives and comprising a primary amine
    WO2016139285A1|2016-09-09|Tyre comprising a composition comprising a derivative of zinc diacrylate and a peroxide
    WO2015124684A1|2015-08-27|Rubber composition comprising a plasticising system based on hydrocarbonated resin having a low glass transition temperature
    WO2015124681A1|2015-08-27|Rubber composition comprising a plasticising system based on a blend of hydrocarbonated resin having a low and a high glass transition temperature
    FR2984895A1|2013-06-28|PNEUMATIC COMPRISING A COMPOSITION ESSENTIALLY FREE OF GUANIDIC DERIVATIVE AND COMPRISING AN ALKALI OR ALKALINE-EARTH METAL HYDROXIDE
    WO2013092528A1|2013-06-27|Tyre comprising a composition essentially free of guanidine derivative and comprising a hydroxyalkylpiperazine
    WO2015124679A1|2015-08-27|Rubber composition comprising a plasticising system based on oil and hydrocarbonated resin having a low glass transition temperature
    WO2013092525A1|2013-06-27|Tyre comprising a composition essentially free of guanidine derivative and comprising a primary ether amine
    WO2013092526A1|2013-06-27|Tyre comprising a composition essentially free of guanidine derivative and comprising an aminoether alcohol
    WO2014180673A1|2014-11-13|Tire having a composition that is essentially free of guanidine derivatives and including a triazine compound and a primary amine
    FR2984899A1|2013-06-28|PNEUMATIC COMPRISING A COMPOSITION ESSENTIALLY FREE OF GUANIDIC DERIVATIVE AND COMPRISING A HYDROXYLATED DIAMINE
    FR3005470A1|2014-11-14|PNEUMATIC COMPRISING A COMPOSITION ESSENTIALLY FREE OF GUANIDIC DERIVATIVE AND COMPRISING A TRIAZINE COMPOUND AND AN ALKALI OR ALKALINE EARTH METAL HYDROXIDE
    WO2014095589A1|2014-06-26|Tyre comprising a composition essentially free of guanidine derivative and comprising a thiazole compound and a primary amine
    FR2999584A1|2014-06-20|PNEUMATIC COMPRISING A COMPOSITION ESSENTIALLY FREE OF GUANIDIC DERIVATIVE AND COMPRISING A THIAZOLE COMPOUND AND AN ALKALI OR ALKALINE EARTH METAL HYDROXIDE
    WO2014180674A1|2014-11-13|Tire having a composition that is essentially free of guanidine derivatives and including a triazine compound and a primary etheramine
    同族专利:
    公开号 | 公开日
    CN107001704A|2017-08-01|
    EP3237227A1|2017-11-01|
    JP6742317B2|2020-08-19|
    FR3030543B1|2017-01-13|
    US20170349728A1|2017-12-07|
    US10457793B2|2019-10-29|
    WO2016102480A1|2016-06-30|
    EP3237227B1|2019-03-27|
    JP2018502191A|2018-01-25|
    CN107001704B|2018-10-26|
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    法律状态:
    2015-12-21| PLFP| Fee payment|Year of fee payment: 2 |
    2016-06-24| PLSC| Search report ready|Effective date: 20160624 |
    2016-12-22| PLFP| Fee payment|Year of fee payment: 3 |
    2017-12-21| PLFP| Fee payment|Year of fee payment: 4 |
    2019-09-27| ST| Notification of lapse|Effective date: 20190906 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1463045A|FR3030543B1|2014-12-22|2014-12-22|PNEUMATIC COMPRISING A COMPOSITION COMPRISING A POLYFUNCTIONAL ACRYLATE DERIVATIVE AND A PEROXIDE|FR1463045A| FR3030543B1|2014-12-22|2014-12-22|PNEUMATIC COMPRISING A COMPOSITION COMPRISING A POLYFUNCTIONAL ACRYLATE DERIVATIVE AND A PEROXIDE|
    JP2017532107A| JP6742317B2|2014-12-22|2015-12-21|Tire containing composition comprising polyfunctional acrylate derivative and peroxide|
    US15/538,347| US10457793B2|2014-12-22|2015-12-21|Tire comprising a composition comprising a polyfunctional acrylate derivative and a peroxide|
    EP15821071.6A| EP3237227B1|2014-12-22|2015-12-21|Tyre comprising a composition comprising a polyfunctional acrylate derivative and a peroxide|
    PCT/EP2015/080817| WO2016102480A1|2014-12-22|2015-12-21|Tyre comprising a composition comprising a polyfunctional acrylate derivative and a peroxide|
    CN201580065163.0A| CN107001704B|2014-12-22|2015-12-21|Include the tire of the composition containing polyfunctional acrylic ester derivative and peroxide|
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